RTFM, man:
If any party member is in any of the following states, that party cannot request or accept party duels:
* When in combat or duel, or chaotic state
* When participating in the Olympiad Games
* During private store or private manufacture
* When HP/MP is below 50% (including death)
* When in a siege (clan or ally participating in a siege)
* When the one challenged to a party duel is a member of the challenger's party
* When in a zone where restarting is prohibited
* When inside a siege war zone
* When the challenge requester and recipient are more than a certain distance apart
* When there is no empty space in the party-use arena
* When the challenge recipient is in an opponent’s hall during a siege
* When riding something a strider or wyvern
* When in a peace zone or battle zone